Final Recap
We use natural units throughout.
Classical System
- Given the force laws and suitable initial position and velocity, the equations determine future and past motion wherever a unique solution exists.
- Newtonian Formulation
- For a constant-mass particle in an inertial frame, .
- Tracking forces and constraints can become cumbersome in complicated systems.
- The vector law does not depend on a particular choice of Cartesian axes; its component expressions depend on the coordinates used.
- Lagrangian Formulation
- For ordinary particles with standard kinetic energy and a velocity-independent potential, . More general systems can require other forms of .
- Action: .
- Physical trajectories make the action stationary: . A stationary point need not be a minimum or maximum.
- Stationary action gives the Euler–Lagrange equations: .
- The usual variational derivation fixes the endpoint positions. These are boundary conditions for the variation, not initial conditions for predicting motion; we normally solve the resulting equations using initial positions and velocities.
- We choose generalized coordinates and encode the dynamics in , often avoiding explicit constraint forces.
- Hamiltonian Formulation
- Define the canonical momenta . When these relations can be inverted for the velocities, use as phase-space coordinates.
- The Hamiltonian is , with the velocities expressed in terms of . For standard kinetic energy and a velocity-independent potential in time-independent coordinates, ; this equality is not universal.
- For each degree of freedom, replace a second-order ordinary differential equation with two first-order ordinary differential equations: and .
- The system follows a trajectory in phase space. Along that trajectory, , so stays constant when it has no explicit time dependence.
Quantum System
- A quantum state generally predicts a distribution of measurement outcomes. Position and momentum cannot both have arbitrarily sharp distributions. An isolated state's evolution under the Schrödinger equation is deterministic, even though individual measurement outcomes are generally probabilistic.
- A pure state is represented by a normalized vector , up to an overall phase. A single measurement does not reveal that entire vector; mixed states require density operators.
- Observables are self-adjoint linear operators (Hermitian matrices in finite dimensions), so their possible measured values are real.
- A linear operator maps vectors in its domain to vectors. Its output need not be normalized and can be zero, so it is not automatically another physical state.
- An eigenvector satisfies : the operator maps the nonzero vector to a scalar multiple of itself, and is its eigenvalue. General operators can have complex eigenvalues, but self-adjoint observables have real ones.
- For an observable with a discrete orthonormal eigenbasis, expand the state itself as , where .
- For a nondegenerate eigenvalue , the probability of measuring it is . The coefficient is a probability amplitude. For a degenerate eigenvalue, sum over an orthonormal basis of its eigenspace.
- Applying to a state is not a model of performing a measurement. In an ideal projective measurement, the observed outcome selects an eigenspace, and projection followed by normalization gives the conditional state after measurement.
- Useful examples of observables:
- Position: possible outcomes are positions in space. In the position representation, .
- Momentum: possible outcomes are momenta. In the position representation for a particle on a line, .
- The wavefunction expresses the state in the position basis. It is not the result of applying to the state.
- The momentum-space wavefunction expresses the same state in a different basis. A Fourier transform relates these two wavefunctions.
- Position and momentum on an infinite line have continuous spectra and use generalized eigenstates. Here is a probability density: the probability of finding the particle in a region is .
- Evolution of a quantum system
- The initial state determines how an isolated system evolves, so we usually study its time dependence.
- The Schrödinger equation governs the time evolution of the state: .
- Harmonic Oscillator
Important model system and the basis for ladder-operator quantization
Restoring force proportional to displacement:
Potential energy is quadratic about equilibrium:
Hamiltonian: , where
Constant-energy trajectories are ellipses in ordinary phase space and circles after rescaling the axes
Quantization promotes and to operators satisfying . Define
which obey .
With the number operator ,
The ground state satisfies , and the normalized number states are .
The ladder operators act as
giving the discrete spectrum . The ground state therefore has nonzero zero-point energy .
- First Quantization
- In canonical quantization, promote position and momentum to operators satisfying , then construct the Hamiltonian operator from them.
- Products involving noncommuting variables can introduce operator-ordering ambiguities.
- Special Relativity
Particle physics often involves particles moving near the speed of light, so relativistic effects must be included.
Lorentz transformations relate spacetime coordinates in different inertial frames with a common origin.
For a boost with relative velocity along the direction,
The inverse boost is obtained by replacing . Unlike a Galilean transformation, a Lorentz boost mixes space and time and preserves the speed of light.
The Minkowski metric with signature gives the invariant spacetime interval squared: .
Energy and three-momentum form the four-momentum , which transforms as a four-vector under Lorentz transformations.
Under the same boost,
Its invariant squared norm is , where is the rest mass.
- Klein–Gordon Equation
- The Klein–Gordon equation follows from the relativistic energy–momentum relation by substituting and , giving .
- Has positive- and negative-frequency plane-wave solutions, with . In quantum field theory, these are interpreted through particle and antiparticle modes with positive physical energies. For a real scalar field, the particle is its own antiparticle.
- Is second order in time, so specifying a solution requires both and initially.
- Its conserved density is not positive definite, so it cannot serve as an ordinary position probability density. For a complex field, it is interpreted as a charge density.
- Describes spin-0 fields; particles with other spins require different field equations.
- Plane-Wave Solutions
- A free particle with definite momentum has a plane wave , where and in natural units.
- Nonrelativistic: this solves the free Schrödinger equation when the kinetic energy is . The corresponding relativistic total energy has the low-momentum expansion .
- Relativistic: a free scalar field has plane-wave solutions , where and is Lorentz invariant. These solve the Klein–Gordon equation when .
- A single plane wave extends throughout space and is not square-normalizable on infinite space; superpositions can form localized, normalizable wave packets.
- Free Dirac Equation
- The Dirac equation factorizes the Klein–Gordon operator using gamma matrices, which satisfy the Clifford algebra .
- Is first order in time and space: .
- Applying shows that the free Dirac equation implies , where . Thus each spinor component satisfies the Klein–Gordon equation, and plane-wave solutions satisfy . The Klein–Gordon equation alone does not imply the Dirac equation.
- Has a nonnegative conserved probability density in the single-particle interpretation.
- Describes spin- particles.
- Still has positive- and negative-energy solutions; quantum field theory interprets these through particles and antiparticles with positive physical energies.
- General solution
Because the free Dirac equation is linear, its general solution is a superposition of all momentum, spin, and frequency modes:
Here . The terms are positive-frequency modes and the terms are negative-frequency modes, with two spin labels for each momentum.
For a classical Dirac field, and are numerical amplitudes fixed by the initial field. In quantum field theory they become electron-annihilation and positron-creation operators, respectively.
The field is therefore a superposition of independent momentum–spin modes. After quantization, each mode behaves as a fermionic oscillator, governed by anticommutation relations rather than the commutation relations of an ordinary bosonic harmonic oscillator.
- Spin
- Spin is intrinsic angular momentum associated with how the Dirac spinor transforms under rotations; it is not literal rotation of a particle. Angular momentum conservation reveals why orbital angular momentum alone is insufficient.
- For the free Dirac Hamiltonian , with and , orbital angular momentum is not separately conserved: in general.
- Spin operator: , where in the Dirac representation and are the Pauli matrices. It obeys and , corresponding to spin .
- Total angular momentum is conserved: . More precisely, the two commutators cancel, , although neither nor is separately conserved in general.
- Along the axis, the two-component spin basis is and , with .
- Positive-frequency spinor solutions have the form , where and .
- For , in the Dirac representation one choice is , normalized so that . The label specifies the rest-frame spin projection; a moving spinor need not be an eigenvector of .
- Negative-frequency solutions are with and . In quantum field theory, these modes enter the antiparticle part of the field.
- A Dirac spinor has four components, but the free equation leaves two independent spin states for each energy branch. Under a spatial rotation, a spinor changes sign; it returns to itself after .
Classical Field to Quantum Field
A classical field assigns a number, vector, or spinor to every spacetime point. Examples include a scalar field , the electromagnetic field , and a Dirac spinor .
Its dynamics follow from an action . Stationary action gives the field Euler–Lagrange equation
A free field obeys a linear equation, so it can be decomposed into independent Fourier modes. For a free scalar field, each momentum mode satisfies
which has the same form as a harmonic oscillator with frequency .
Canonical field quantization promotes the classical field and its conjugate momentum to operators with the equal-time relation
Equivalently, promote each mode amplitude to creation and annihilation operators. A free real scalar field becomes
with .
The vacuum satisfies . Acting with creates one particle of momentum and energy ; repeated creation operators build multiparticle Fock states.
The free-field Hamiltonian is a sum of oscillator Hamiltonians. In a finite box with discrete momenta, it has the schematic form . The terms make up the vacuum energy, and each excitation above the vacuum is one particle quantum of a field mode.
Bosonic fields use commutators and permit any occupation number. Dirac fields use anticommutators, so each momentum–spin particle or antiparticle mode can have occupation number only or .
In a free theory the momentum modes evolve independently. Interactions couple the fields and allow quanta to be created, destroyed, or scattered while conserving the symmetries' associated quantities.
Free Lagrangian Densities
Real scalar field — Klein–Gordon
The Euler–Lagrange equation is . After quantization, the field describes neutral spin- bosons; a real scalar particle is its own antiparticle. A complex scalar field instead uses and can carry a conserved charge.
Dirac field
Varying gives ; varying gives the adjoint Dirac equation. After quantization, describes spin- fermions and is its Dirac adjoint. Particle and antiparticle modes obey anticommutation relations.
Electromagnetic field — Maxwell
The Euler–Lagrange equation is the source-free Maxwell equation . The Lagrangian is invariant under the gauge transformation . After quantization, the field describes massless spin- photons with two physical transverse polarizations.
Adding an external conserved current gives the interaction term and changes Maxwell's equation to .
Each free Lagrangian is quadratic in its field, so its equation of motion is linear and its momentum modes evolve independently. Interaction terms contain products of fields and couple those modes.
Fermion and Photon Quantization
Quantizing the Dirac field promotes its mode amplitudes to operators:
Here annihilates a fermion and creates its antifermion.
Fermionic modes obey canonical anticommutation relations:
with all other anticommutators zero. Consequently, for a fixed mode, implementing the Pauli exclusion principle and restricting each mode's occupation to or .
The vacuum satisfies . The operators and create particle and antiparticle states. After normal ordering, the free Hamiltonian is a sum of positive-energy particle and antiparticle number operators.
The Maxwell field has gauge redundancy, so its four potential components do not represent four physical photon polarizations. For external physical photons, one may use the transverse-mode expansion
where and labels the two physical polarizations.
Photon operators obey bosonic commutation relations,
so any number of photons may occupy the same mode.
Covariant perturbation theory adds the gauge-fixing term
In Feynman gauge, , the internal photon propagator is . Four formal components appear internally, but gauge invariance ensures that only the two physical transverse polarizations contribute to observable external photon states.
The rest of the recap builds the Standard Model Lagrangian from matter- and gauge-field kinetic terms, gauge interactions, the Higgs sector, and Yukawa interactions. After electroweak symmetry breaking, the Higgs and Yukawa terms generate masses for the massive gauge bosons and fermions.
Electromagnetic Field and QED
The free Dirac and Maxwell Lagrangians describe electrons and photons propagating independently. Quantum electrodynamics (QED) adds the interaction between them.
Global symmetry: the free Dirac Lagrangian is invariant under a constant phase rotation
Noether's theorem associates this symmetry with the conserved electric current , satisfying . Its conserved charge is .
Local symmetry: if the phase becomes position dependent, , differentiating produces an extra term, so the ordinary derivative does not transform covariantly.
Introduce the electromagnetic gauge field and the covariant derivative
Under
the covariant derivative transforms as . The gauge field compensates for the position-dependent phase.
The field strength
is gauge invariant. The term supplies the gauge field's dynamics and gives Maxwell's equations.
The complete QED Lagrangian is
Expanding separates it into
The interaction is . It allows a charged fermion to emit or absorb a photon and gives the QED vertex factor . Charge and four-momentum are conserved at each vertex.
Because is Abelian, contains no terms quadratic in ; therefore QED has no elementary photon-only interaction vertex. Photons can still scatter indirectly through charged-particle loops.
A photon mass term is not gauge invariant, so unbroken electromagnetic requires the photon to be massless. Quantizing leaves two physical transverse photon polarizations.
Weak Interaction
Experiments such as beta decay show that the weak interaction violates parity, which reverses spatial coordinates and momenta: and . Spin is unchanged under parity, so the correlation changes sign. The observed asymmetry means the weak interaction distinguishes left from right.
Define
These chiral projectors satisfy , , , and . They split a Dirac field into and .
Chirality is a Lorentz-transformation property of a spinor and is distinct from spin projection. For massless particles it agrees with helicity; for massive particles, a state of definite helicity generally contains both chiralities.
The charged weak interaction couples only to left-chiral fermion fields. A left-chiral neutrino field annihilates negative-helicity neutrinos and creates positive-helicity antineutrinos in the massless limit. There is no corresponding right-chiral charged current.
For the electron and electron neutrino, the left-chiral current and its conjugate are
The analogous quark current changes a down quark into an up quark. These currents account for the species changes in beta decay.
Group the left-chiral fields into weak-isospin doublets
A global transformation acts as , where and . The Pauli matrices here mix the two species in a doublet; they do not act on spin.
Making the symmetry local, , requires one gauge field for each of the three generators. Define
where is the weak coupling and are the three gauge fields. Because this symmetry acts on left-chiral doublets, it is called ; right-chiral charged fermions are singlets.
The combinations
are the charged weak fields. The third field is neutral. Before electroweak mixing, is not yet the physical boson or photon.
Expanding the covariant derivative gives the lepton interaction
The first line contains the charged-current interactions, which exchange an electron and neutrino through . The second line is the neutral interaction; electroweak mixing later turns the neutral gauge fields into the physical and photon.
The field strength and gauge-field kinetic term are
The extra product of gauge fields appears because is non-Abelian. It produces direct three- and four-gauge-boson interactions, unlike the Abelian photon field in QED.
Local symmetry forbids an explicit mass term for the gauge fields. In the full electroweak theory, the Higgs mechanism gives masses to and while leaving the photon massless.
Electromagnetic and Weak Terms So Far
Collect the first-generation fermions as and the left-chiral doublets as
The electromagnetic current is
where is the electric charge of each field.
A compact bookkeeping summary of the free gauge fields, free fermions, and interactions introduced so far is
The terms have the following roles:
- : photon propagation.
- : weak gauge-boson propagation and self-interactions.
- : free fermion propagation in the broken-phase, low-energy description.
- : photon coupling to every electrically charged fermion.
- : weak couplings to left-chiral lepton and quark doublets.
Rewriting and as exposes the charged-current part
This is an intermediate bookkeeping expression, rather than the final gauge-invariant electroweak Lagrangian. In particular, the displayed fermion masses belong to the broken-phase, low-energy description. Before symmetry breaking, electromagnetism and the weak interaction are organized as , with a hypercharge field instead of a separate photon field and with fermion masses replaced by Yukawa couplings to the Higgs. The Higgs mechanism later mixes and into the physical photon and , and generates the fermion and massive gauge-boson mass terms.
Electroweak Unification
The neutral field cannot be the photon because its couplings have the wrong pattern:
Fermion component Coupling to Required photon coupling nonzero nonzero The photon must couple equally to and because they are two chiral components of the same charged electron, while it must not couple to the neutrino. The field instead couples only according to weak isospin .
Add a second symmetry, weak hypercharge , with generator . Electric charge is then
Hypercharge supplies the common offset that alone lacks. In the convention , the minimal Standard Model assignments for each generation and the Higgs are
Multiplet The same gauge assignments repeat for all three generations. The minimal model contains no right-chiral neutrino; adding for a Dirac neutrino mass would make it a complete gauge singlet with .
Making local introduces the hypercharge gauge field with coupling . For a field with weak isospin generators and hypercharge ,
The electroweak gauge group is therefore .
Neither nor alone has the correct photon coupling. Define the weak mixing angle , with and , and rotate the two neutral fields:
The couplings obey
so the coefficient becomes . Thus couples to electric charge with the universal interaction .
The orthogonal field couples to the neutral weak current:
for a chiral component with quantum numbers and . Unlike the photon, the generally couples differently to left- and right-chiral fermions.
Electroweak unification reorganizes four gauge fields without changing their number:
The Higgs mechanism later makes and massive while leaving the photon massless.
Electroweak Lagrangian So Far
Before adding the Higgs field, the gauge-invariant electroweak theory contains the fields , the hypercharge field , and the chiral fermion multiplets. For one generation,
The electroweak gauge and fermion Lagrangian is
with
For right-chiral singlets, , so only the hypercharge part of acts.
After defining and rotating into , the fermion interactions can be collected as
where, for the first generation,
The sum in runs over chiral fermion components; for right-chiral singlets.
The three interaction terms describe:
- Electromagnetism: the photon couples universally to electric charge .
- Charged weak interaction: couples only to left-chiral doublets and changes one doublet member into the other.
- Neutral weak interaction: couples to both electric charge and weak isospin, so its left- and right-chiral couplings differ.
The gauge kinetic term also produces , , and four-gauge-boson interactions after the field rotation. These follow from the non-Abelian field strength.
This is the electroweak Lagrangian before the Higgs and Yukawa sectors. Explicit fermion, , and mass terms are absent because they would violate gauge invariance. The Higgs field supplies those masses through spontaneous symmetry breaking while preserving a massless photon.
Higgs Mechanism
- The Higgs mechanism allows gauge bosons and fermions to acquire mass while the underlying Lagrangian remains gauge invariant.
Spontaneous Symmetry Breaking: Global Example
Begin with a complex scalar field and a symmetric potential
The Lagrangian is invariant under the global transformation .
The origin is unstable. Minimizing the potential gives a circle of degenerate vacua,
Choose one vacuum, for example . The laws retain the symmetry, but the chosen vacuum does not. This is spontaneous symmetry breaking.
Expand around the chosen vacuum:
The radial fluctuation is massive, while the angular fluctuation is a massless Goldstone boson:
A broken continuous global generator produces a massless Goldstone mode.
Local Higgs Mechanism
Now make the symmetry local by introducing a gauge field :
This is a toy gauge field used to demonstrate the mechanism; it is not the physical photon of the electroweak theory.
Write the scalar in polar form,
A local gauge transformation can set . In unitary gauge,
Gauge fixing removes the redundant phase from the scalar-field description; it does not discard a physical degree of freedom.
Substitution into the scalar kinetic term gives
The term is a vector mass term, so
The Goldstone degree of freedom becomes the longitudinal polarization of the massive vector. The counting is preserved: a massless vector has two polarizations and the complex scalar has two real modes; afterward, the massive vector has three polarizations and one real scalar remains.
Proca Equation After Higgs Generates a Vector Mass
Keeping the free vector terms in unitary gauge gives
The Maxwell derivative is ; differentiating the generated mass term gives . The Euler–Lagrange equation therefore gives the Proca equation,
Taking the divergence eliminates the antisymmetric field-strength term. For , the equation forces . Substituting this constraint back gives
In the rest frame, leaves three spatial polarizations. The longitudinal mode is physical. The free massive equation forces the constraint; we do not choose it as a gauge condition.
Higgs explains the origin of the mass and longitudinal mode; Proca describes the resulting free massive vector. After electroweak symmetry breaking, the free and fields have Proca equations, while the photon remains massless and obeys Maxwell. Interactions add terms to these free equations. See the derivation in the Higgs chapter.
Standard Model Higgs Field
The electroweak Higgs field is a complex doublet with hypercharge :
Choose the vacuum and unitary-gauge field as
The vacuum is electrically neutral because . Thus is reduced to the unbroken electromagnetic .
The doublet contains four real degrees of freedom. Three Goldstone modes supply the longitudinal polarizations of , , and . The remaining radial excitation is the physical Higgs boson, with
Gauge-Boson Masses
The Higgs kinetic term uses
Evaluated at the vacuum, it produces
In the basis,
Consequently, at tree level,
The vacuum gives mass to the three gauge fields associated with broken generators. The photon corresponds to the unbroken charge generator and remains massless.
Fermion Masses
A direct fermion mass term is not electroweak gauge invariant because and transform differently. Instead, introduce gauge-invariant Yukawa interactions. For the electron,
Substituting the Higgs vacuum gives
so
Other charged fermions acquire masses in the same way. The Higgs mechanism relates each Higgs–fermion coupling to , but the Yukawa constants remain independent measured parameters. Neutrino masses require an extension of the minimal massless-neutrino model used here.
Electroweak Lagrangian Including the Higgs
Combining the gauge, fermion, Higgs, and Yukawa terms gives the electroweak Lagrangian developed so far. For one fermion generation,
where
and contains the and gauge fields with the generators and hypercharge appropriate to each multiplet.
This single expression contains:
- free propagation and self-interactions of the electroweak gauge fields;
- electroweak interactions of leptons and quarks;
- Higgs propagation, its potential, and its gauge interactions;
- Yukawa interactions that become charged-fermion masses and Higgs–fermion couplings after symmetry breaking.
For all three generations, each fermion multiplet acquires a generation index and the Yukawa couplings become matrices. Diagonalizing those matrices produces the observed fermion masses and quark mixing in the charged weak current.
Is only QCD missing? For the minimal, gauge-invariant classical Standard Model Lagrangian, QCD is the remaining force sector. It adds the gluon kinetic term and the colour part of the quark covariant derivative. Once those terms and all three generations are included, the core Standard Model Lagrangian is complete.
Some additions depend on what is being calculated:
- Gauge-fixing and ghost terms are required for perturbative quantization but are not part of the compact gauge-invariant classical expression.
- The minimal Standard Model written here has massless neutrinos. Observed neutrino masses require an extension, such as right-chiral neutrinos or an effective higher-dimensional operator.
- Gravity is not part of the Standard Model.
Quantum Chromodynamics
- Quantum chromodynamics (QCD) is the gauge theory of quarks, gluons, and the strong interaction.
Quarks, Flavours, and Colours
Quarks are spin- fermions. There are six flavours, arranged by their electric charges:
Type Flavours Electric charge Up-type Down-type Flavour identifies the quark species. The strong interaction preserves flavour at a quark–gluon vertex; weak charged currents can change an up-type flavour into a down-type flavour.
Every flavour has three colour components, conventionally labelled red, green, and blue:
These labels have no connection to visible colour. A colour transformation acts on this three-component internal index while leaving the quark's flavour, spinor index, and electric charge unchanged.
Observable hadrons are colour singlets. Mesons contain quark–antiquark colour combinations, while baryons contain an antisymmetric combination of three colours. Isolated quarks and gluons are not observed at long distances; this is confinement.
Local Symmetry
The three colour components have the same free kinetic form, so the free quark Lagrangian is invariant under global colour rotations
The group has eight Hermitian, traceless generators , normalized by
The nonzero structure constants show that is non-Abelian.
Making the colour transformation local introduces eight gluon gauge fields and the strong coupling :
Expanding the covariant derivative gives the quark–gluon interaction
with vertex factor . A gluon interaction can change a quark's colour but not its flavour or electric charge.
Gluons and the QCD Lagrangian
Define the gluon field strength by
The last term occurs because is non-Abelian. Squaring the field strength produces both three-gluon and four-gluon vertices, so gluons interact directly with one another.
The QCD Lagrangian is
The masses arise from the Higgs Yukawa couplings. Both left- and right-chiral quarks carry colour and therefore couple to gluons.
The Higgs is a colour singlet, so its vacuum does not break and the gluons have no mass term. They remain massless in the Lagrangian even though confinement prevents isolated gluons from appearing as asymptotic particles.
The effective strong coupling decreases at high energies or short distances: asymptotic freedom. It grows at hadronic distances, where perturbation theory fails and nonperturbative methods such as lattice QCD are needed.
Minimal Gauge-Invariant Standard Model
The complete Standard Model gauge group is
Colour, weak isospin, and hypercharge act on different internal indices. Quarks carry all three types of charge; leptons and the Higgs are colour singlets.
All gauge interactions can be written in one covariant derivative:
A generator is zero when the field is a singlet under that group.
Combining QCD with the electroweak and Higgs sectors gives
The sum runs over the left-chiral doublets and right-chiral singlets of all three generations, including the three colour components of each quark field.
For three generations, the Yukawa sector is
where are generation indices. After symmetry breaking, these matrices produce fermion masses and the CKM quark-mixing matrix.
This is the compact minimal gauge-invariant classical Standard Model Lagrangian. It omits gauge-fixing and ghost terms used in perturbative calculations, the optional strong-CP term, gravity, and any extension required to generate neutrino masses.
Using the Lagrangian
The Lagrangian specifies the fields, their free propagation, and their interactions. To predict an experiment, follow the chain
From the Lagrangian to the -Matrix
Split the Lagrangian into free and interaction parts,
The quadratic part determines particle states and propagators. The interaction terms determine which particles can meet at a vertex and the strength and tensor structure of that interaction.
The -matrix maps an incoming free-particle state in the distant past to an outgoing free-particle state in the distant future. The transition amplitude is .
Probability conservation requires the -matrix to be unitary, . This relates different scattering contributions and ensures that the probabilities of all possible outcomes sum consistently.
In the interaction picture,
where denotes time ordering. Expanding the exponential gives the Dyson series:
If an interaction carries coupling , a term with insertions is generally of order .
Wick's theorem rewrites time-ordered products as normal-ordered products plus contractions. The contractions are free-field propagators, and the remaining fields attach to the external particle states. Feynman diagrams organize these contributions:
- external lines represent specified incoming and outgoing particles;
- internal lines represent propagators and need not satisfy the on-shell relation;
- vertices come from ;
- loops represent integrations over undetermined internal momenta.
The Feynman rules convert each allowed diagram into an algebraic expression. Add the amplitudes of all diagrams leading to the same final state before taking the absolute square, so interference is retained.
Invariant Amplitude
Separate free passage from the interacting part using
The four-dimensional delta function enforces total energy–momentum conservation. The remaining quantity is the invariant amplitude.
The probability is built from . For unobserved quantum numbers, sum over final spins, colours, and polarizations and average over the corresponding initial ones:
Identical final-state particles also require the appropriate symmetry factor to avoid overcounting equivalent configurations.
Scattering Cross Section
The cross section measures the probability of scattering after dividing out the incoming beam flux. For a process particles,
For a process in the centre-of-momentum frame,
Integrating over the allowed solid angle gives the total cross section. Experimental event counts satisfy , where is the integrated luminosity, up to detector efficiency and acceptance.
Perturbative Accuracy
- Keeping only the lowest nonzero power of a coupling gives the leading-order or tree-level prediction. Loop diagrams give higher-order quantum corrections and generally require regularization and renormalization.
- A perturbative expansion is useful only when the relevant running coupling is sufficiently small. This works well for QED and many high-energy electroweak or QCD processes, but long-distance QCD requires nonperturbative methods.
- Gauge theories also require gauge fixing to define propagators. Ghost fields appear in non-Abelian perturbation theory and cancel unphysical gauge contributions; only gauge-independent observables such as cross sections are physical.